{"id":9310,"date":"2024-08-23T09:23:10","date_gmt":"2024-08-23T09:23:10","guid":{"rendered":"https:\/\/longchangextracts.com\/?p=9310"},"modified":"2024-08-23T09:23:10","modified_gmt":"2024-08-23T09:23:10","slug":"modified-starch-3","status":"publish","type":"post","link":"https:\/\/longchangextracts.com\/tr\/modified-starch-3\/","title":{"rendered":"Modifiye ni\u015fastan\u0131n m\u0131s\u0131r i\u00e7eceklerinin stabilitesi \u00fczerindeki etkisi nedir?"},"content":{"rendered":"

M\u0131s\u0131r besin a\u00e7\u0131s\u0131ndan zengindir, bile\u015fimi nispeten eksiksizdir, kalsiyum, magnezyum, selenyum, demir, karoten, vitaminler ve di\u011fer temel besinler a\u00e7\u0131s\u0131ndan zengin olmas\u0131n\u0131n yan\u0131 s\u0131ra protein (8%-14%), ya\u011f (3.5%-5.7%, linoleik asit 60%'ye kadar) a\u00e7\u0131s\u0131ndan da zengindir ve sadece ni\u015fasta i\u00e7eri\u011fi 64%-78% kadar y\u00fcksektir.<\/p>\n

M\u0131s\u0131r i\u00e7ece\u011finde bulunan bu makromolek\u00fcller (\u00f6rne\u011fin ni\u015fasta ve protein) tipik bir termodinamik karars\u0131z sistemdir, bu nedenle \u00fcretim s\u00fcrecinde ve raf depolama d\u00f6neminde agl\u00fctinasyon ve \u00e7\u00f6kelme delaminasyonunun meydana gelmesi \u00e7ok kolayd\u0131r, b\u00f6ylece m\u0131s\u0131r i\u00e7ece\u011finin bulan\u0131k ve kararl\u0131 durumu kaybolur, bu da i\u00e7ece\u011fin duyusal kalitesinin d\u00fc\u015fmesine neden olur.<\/p>\n

Uygun modifikasyon i\u015flemi ile elde edilen modifiye ni\u015fastalar\u0131n \u00e7o\u011fu, d\u00fc\u015f\u00fck yap\u0131\u015ft\u0131rma s\u0131cakl\u0131\u011f\u0131, y\u00fcksek \u015feffafl\u0131k, y\u00fcksek viskozite ve iyi stabilite, k\u00fc\u00e7\u00fck p\u0131ht\u0131la\u015fma, iyi donma direnci, iyi film olu\u015fturma \u00f6zelliklerinin yan\u0131 s\u0131ra asit direnci, alkali direnci ve g\u00fc\u00e7l\u00fc mekanik \u00f6zellikler gibi bir\u00e7ok m\u00fckemmel \u00f6zelli\u011fe sahiptir.<\/p>\n

\u015eu anda, hidroksipropil bile\u015fik modifiye ni\u015fasta, asetillenmi\u015f modifiye ni\u015fasta ve hidroksipropil oktenil s\u00fcksinat ni\u015fastas\u0131 daha fazla ara\u015ft\u0131rma ile g\u0131dalarda uygulanm\u0131\u015ft\u0131r, ancak tah\u0131l i\u00e7eceklerinde kullan\u0131mlar\u0131 hakk\u0131nda \u00e7ok az rapor vard\u0131r.<\/p>\n

Modifiye ni\u015fasta uygulamas\u0131n\u0131 tah\u0131l i\u00e7eceklerinin i\u015flenmesiyle daha iyi birle\u015ftirmek amac\u0131yla, bu deney, m\u0131s\u0131r i\u00e7eceklerinin stabilitesini art\u0131rmak i\u00e7in m\u0131s\u0131r i\u00e7eceklerine eklenecek stabilizat\u00f6rler olarak yukar\u0131daki \u00fc\u00e7 modifiye ni\u015fastay\u0131 se\u00e7meyi ve b\u00f6ylece m\u0131s\u0131r i\u00e7eceklerinin \u00fcretimi ve i\u015flenmesi i\u00e7in teorik bir temel ve i\u015flem parametreleri sa\u011flamay\u0131 ama\u00e7lamaktad\u0131r.<\/p>\n

Hidroksipropil bile\u015fik modifiye ni\u015fastan\u0131n etkisi<\/strong>
\nM\u0131s\u0131r i\u00e7ece\u011finin stabilitesi \u00fczerine etkisi<\/strong><\/p>\n

\u015eekil 1'den g\u00f6r\u00fclebilece\u011fi gibi, hidroksipropil modifiye ni\u015fastan\u0131n artmas\u0131yla m\u0131s\u0131r i\u00e7ece\u011finin \u0131\u015f\u0131k absorpsiyon stabilitesi artm\u0131\u015f ve ard\u0131ndan azalm\u0131\u015ft\u0131r ve hidroksipropil modifiye ni\u015fasta miktar\u0131 2.8% oldu\u011funda \u0131\u015f\u0131k absorpsiyon katsay\u0131s\u0131 en b\u00fcy\u00fck olmu\u015ftur; santrif\u00fcj sedimantasyon \u00f6nce azalm\u0131\u015f ve ard\u0131ndan artm\u0131\u015ft\u0131r ve hidroksipropil modifiye ni\u015fasta miktar\u0131 2.8% oldu\u011funda santrif\u00fcj sedimantasyon h\u0131z\u0131 en k\u00fc\u00e7\u00fck olmu\u015ftur ve sistemin viskozitesi orta d\u00fczeydedir.<\/p>\n

Bu durum, ni\u015fastan\u0131n denat\u00fcrasyonundan sonra fonksiyonel bir grup olarak molek\u00fcller aras\u0131 hidrojen ba\u011f\u0131 ile ni\u015fasta molek\u00fcllerinin dehidrasyonunu engelleyen ve modifiye ni\u015fastay\u0131 y\u00fcksek s\u0131cakl\u0131k, y\u00fcksek kesme ve d\u00fc\u015f\u00fck pH ko\u015fullar\u0131 alt\u0131nda y\u00fcksek viskozite ile tutan hidroksipropil grubunun eklenmesine ba\u011flanabilir.<\/p>\n

Hidroksipropil modifiye ni\u015fasta m\u0131s\u0131r i\u00e7eceklerine uyguland\u0131\u011f\u0131nda, m\u0131s\u0131r i\u00e7eceklerindeki baz\u0131 bile\u015fenlerle (\u00f6rne\u011fin ni\u015fasta molek\u00fclleri) a\u011f ba\u011flant\u0131lar\u0131 olu\u015fturabilir. Hidroksil gruplar\u0131 aray\u00fczde toplan\u0131r ve m\u0131s\u0131r i\u00e7ece\u011findeki bile\u015fenlerle kimyasal olarak birle\u015fir, bu da bile\u015fenler aras\u0131ndaki hidrasyonu art\u0131r\u0131r, a\u011fdaki protein molek\u00fcllerini stabilize eder, m\u0131s\u0131r i\u00e7ece\u011findeki orijinal ni\u015fasta molek\u00fclleri aras\u0131ndaki hidrojen ba\u011f\u0131n\u0131 zay\u0131flat\u0131r ve suyun serbest hareketini engeller, b\u00f6ylece t\u00fcm sistem su sabitleme ve s\u00fcspansiyon stabilizasyonu etkisini elde eder.<\/p>\n

Bu nedenle, m\u0131s\u0131r i\u00e7ece\u011fine 2.8% hidroksipropil bile\u015fik modifiye ni\u015fasta eklendi\u011finde m\u0131s\u0131r i\u00e7ece\u011finin stabilitesi en iyi olmu\u015ftur.<\/strong><\/p>\n

Asetillenmi\u015f modifiye ni\u015fasta<\/strong>
\nM\u0131s\u0131r i\u00e7ece\u011finin stabilitesi \u00fczerine etkisi<\/strong><\/p>\n

\u015eekil 2'de g\u00f6r\u00fclebilece\u011fi gibi, asetillenmi\u015f modifiye ni\u015fasta ilavesinin artmas\u0131yla, m\u0131s\u0131r i\u00e7ece\u011finin \u0131\u015f\u0131k absorpsiyon stabilitesi \u00f6nce artm\u0131\u015f, sonra azalm\u0131\u015f ve asetillenmi\u015f modifiye ni\u015fasta ilavesi 2.8 oldu\u011funda maksimuma ula\u015fm\u0131\u015ft\u0131r; santrif\u00fcj \u00e7\u00f6kelmesi \u00f6nce azalm\u0131\u015f, sonra artm\u0131\u015f ve asetillenmi\u015f modifiye ni\u015fasta ilavesi 2.8% oldu\u011funda daha d\u00fc\u015f\u00fck bir seviyede olmu\u015ftur ve sistem viskozitesi orta d\u00fczeydedir ve homojen bulan\u0131kl\u0131k \u015feklindedir.<\/p>\n

Bunun nedeni, asetillenmi\u015f modifiye ni\u015fastan\u0131n iyi su emme ve hidrofilik yetene\u011fe sahip olmas\u0131, m\u0131s\u0131r i\u00e7ece\u011fi kar\u0131\u015ft\u0131rma sisteminde sadece su molek\u00fclleriyle de\u011fil, ayn\u0131 zamanda m\u0131s\u0131r i\u00e7ece\u011findeki b\u00fcy\u00fck molek\u00fcllerle (proteinler gibi), kar\u0131\u015ft\u0131rma sistemi boyunca e\u015fit olarak da\u011f\u0131lm\u0131\u015f k\u00fc\u00e7\u00fck par\u00e7ac\u0131k boyutuna sahip birle\u015fik su, sistemin ilave miktar\u0131ndaki art\u0131\u015fla kademeli olarak stabilize edilir, ancak ilave miktar\u0131 2.8% oldu\u011funda, sistem mezostabil bir duruma ula\u015ft\u0131 ve viskozite tekd\u00fcze bulan\u0131kl\u0131kt\u0131. Bununla birlikte, ilave miktar\u0131 2.8%'ye ula\u015ft\u0131\u011f\u0131nda, sistem mezostabil bir duruma ula\u015f\u0131r, bu s\u0131rada m\u0131s\u0131r i\u00e7ece\u011finin stabilitesi daha iyidir.<\/p>\n

Bu nedenle, 2.8% asetillenmi\u015f modifiye ni\u015fasta i\u00e7eren m\u0131s\u0131r ni\u015fastas\u0131 en iyi stabiliteye sahiptir.<\/strong><\/p>\n

Hidroksipropil oktenil s\u00fcksinat ni\u015fastas\u0131n\u0131n m\u0131s\u0131r i\u00e7eceklerinin stabilitesi \u00fczerine etkisi<\/strong>
\nM\u0131s\u0131r i\u00e7ece\u011finin stabilitesi \u00fczerine etkisi<\/strong><\/p>\n

\u015eekil 3'te g\u00f6r\u00fclebilece\u011fi gibi, hidroksipropil oktenil s\u00fcksinat ni\u015fastas\u0131n\u0131n artmas\u0131yla, m\u0131s\u0131r i\u00e7ece\u011finin \u0131\u015f\u0131k emme kararl\u0131l\u0131\u011f\u0131 \u00f6nce artm\u0131\u015f, sonra azalm\u0131\u015f ve 1.6%'de zirveye ula\u015fm\u0131\u015ft\u0131r; m\u0131s\u0131r i\u00e7ece\u011finin santrif\u00fcj \u00e7\u00f6kelme h\u0131z\u0131 ise 1.4%'de maksimum de\u011fere ve 1.6%'de minimum de\u011fere ula\u015fm\u0131\u015ft\u0131r.<\/p>\n

Bunun nedeni, hidroksipropil oktenil s\u00fcksinat esterle\u015ftirilmi\u015f ni\u015fastan\u0131n, di\u011fer geleneksel yenilebilir modifiye ni\u015fastalar\u0131n aksine, hem lipofilik hem de hidrofilik gruplar i\u00e7eren bir y\u00fczey aktif madde olmas\u0131 ve hidroksipropil oktenil s\u00fcksinat modifiye ni\u015fastan\u0131n lipofilik gruplar\u0131 arac\u0131l\u0131\u011f\u0131yla m\u0131s\u0131r i\u00e7ecek sistemindeki ya\u011f ve su fazlar\u0131n\u0131 birbirine ba\u011flayabilmesi olabilir.<\/p>\n

M\u0131s\u0131r i\u00e7ece\u011fi bir t\u00fcr su i\u00e7inde ya\u011f em\u00fclsiyonudur, m\u0131s\u0131r i\u00e7ece\u011fine hidroksipropil oktenil s\u00fcksinat modifiye ni\u015fasta eklemek em\u00fclsifikasyon ve stabilizasyon rol\u00fcn\u00fc oynayabilir, b\u00f6ylece m\u0131s\u0131r i\u00e7ecek sistemi d\u00fczg\u00fcn ve kararl\u0131 bir dispersiyon veya em\u00fclsiyon olu\u015fturur.<\/p>\n

Bu nedenle, m\u0131s\u0131r i\u00e7ece\u011fine 1.6% hidroksipropil oktenil s\u00fcksinat modifiye ni\u015fasta eklendi\u011finde m\u0131s\u0131r i\u00e7ece\u011fi en iyi stabiliteye sahiptir.<\/strong>\"\" \"\" \"\"<\/p>","protected":false},"excerpt":{"rendered":"

Corn is rich in nutrients, the composition is relatively complete, in addition to rich in calcium, magnesium, selenium, iron, carotene, vitamins and other essential nutrients, but also rich in protein (8%-14%), fat (3.5%-5.7%, of which linoleic acid is up to 60%), and only the content of starch is as high as 64%-78% . 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