{"id":7553,"date":"2024-08-06T20:29:54","date_gmt":"2024-08-06T20:29:54","guid":{"rendered":"https:\/\/longchangextracts.com\/?p=7553"},"modified":"2024-08-06T20:29:54","modified_gmt":"2024-08-06T20:29:54","slug":"bamboo-shoot-shell-lignin","status":"publish","type":"post","link":"https:\/\/longchangextracts.com\/tr\/bamboo-shoot-shell-lignin\/","title":{"rendered":"D\u00fc\u015f\u00fck erime noktal\u0131 \u00e7\u00f6z\u00fcc\u00fc \u00f6n i\u015fleminin bambu filizi kabu\u011fu lignininin yap\u0131s\u0131 ve fizikokimyasal \u00f6zellikleri \u00fczerindeki etkisi"},"content":{"rendered":"

D\u00fc\u015f\u00fck erime noktal\u0131 \u00e7\u00f6z\u00fcc\u00fc \u00f6n i\u015fleminin bambu filizi kabu\u011fu lignininin yap\u0131s\u0131 ve fizikokimyasal \u00f6zellikleri \u00fczerindeki etkisi
\nLignin, fenilpropan yap\u0131sal birimlerinin oksidatif ba\u011flanmas\u0131yla olu\u015fan amorf do\u011fal bir polimerdir. Suda \u00e7\u00f6z\u00fcnmeyen diyet lifinin bile\u015fenlerinden biridir ve metoksi, fenolik hidroksil, alkol hidroksil, karboksil gibi aktif gruplar i\u00e7erir. Y\u00fcksek biyolojik aktiviteye sahiptir. Rodr\u00ed guez gut \u00e9 rrez ve arkada\u015flar\u0131, ligninin sel\u00fcloz ve hemisel\u00fcloza k\u0131yasla safra asitleri i\u00e7in daha g\u00fc\u00e7l\u00fc bir adsorpsiyon kapasitesine sahip oldu\u011funu; Gong ve arkada\u015flar\u0131 ise ligninin alfa amilaz i\u00e7in bir immobilizasyon ta\u015f\u0131y\u0131c\u0131s\u0131 olarak kullan\u0131labilece\u011fini bulmu\u015ftur. Lignin ayr\u0131ca antioksidan, antibakteriyel, UV \u0131\u015f\u0131nlar\u0131na dayan\u0131kl\u0131, g\u00fcne\u015f koruyucu ve cilt bak\u0131m\u0131n\u0131n yan\u0131 s\u0131ra cilt kanserinin engellenmesi gibi g\u00fc\u00e7l\u00fc biyolojik aktivitelere sahiptir. \u0130yi biyouyumlulu\u011fa sahiptir ve g\u0131da ve kozmetik end\u00fcstrilerinde uygulanma potansiyeline sahiptir.
\n\u015eimdiye kadar, lignin ekstraksiyonu i\u00e7in buhar patlamas\u0131, organik \u00e7\u00f6z\u00fcc\u00fc \u00f6n i\u015flemi ve derin \u00f6tektik \u00e7\u00f6z\u00fcc\u00fc (DES) \u00f6n i\u015flem y\u00f6ntemleri de dahil olmak \u00fczere bir dizi kimyasal, mekanik ve biyolojik \u00f6n i\u015flem tekni\u011fi kullan\u0131lm\u0131\u015ft\u0131r. Bununla birlikte, lignini ay\u0131rmak i\u00e7in kullan\u0131lan kimyasal y\u00f6ntemler, \u00e7evre kirlili\u011fine neden olabilecek g\u00fc\u00e7l\u00fc asitler veya bazlar ve y\u00fcksek s\u0131cakl\u0131k ve bas\u0131n\u00e7 ko\u015fullar\u0131 gerektirir. Biyolojik y\u00f6ntemler ise genellikle s\u0131cakl\u0131k ve biyolojik aktivitenin belirsizli\u011fi ile s\u0131n\u0131rl\u0131d\u0131r. D\u00fc\u015f\u00fck erime noktal\u0131 \u00e7\u00f6z\u00fcc\u00fcler veya iyonik s\u0131v\u0131lar olarak da bilinen DES, hidrojen ba\u011f\u0131 don\u00f6rleri ve al\u0131c\u0131lar\u0131ndan olu\u015fan d\u00fc\u015f\u00fck erime noktal\u0131 bir kar\u0131\u015f\u0131md\u0131r. Ma ve arkada\u015flar\u0131n\u0131n ara\u015ft\u0131rmas\u0131, DES \u00e7\u00f6z\u00fcc\u00fclerinin sadece lignini verimli bir \u015fekilde \u00e7\u00f6zmekle kalmay\u0131p ayn\u0131 zamanda sel\u00fclozu da zor \u00e7\u00f6zd\u00fc\u011f\u00fcn\u00fc g\u00f6stermi\u015ftir. Fiziksel ve kimyasal \u00f6zellikleri nedeniyle DES \u00e7\u00f6z\u00fcc\u00fcs\u00fc, bile\u015fenlerinin herhangi birinden daha d\u00fc\u015f\u00fck bir erime noktas\u0131na sahiptir ve oda s\u0131cakl\u0131\u011f\u0131nda s\u0131v\u0131 bir \u00f6tektik sistemdir. DES \u00e7\u00f6z\u00fcc\u00fcs\u00fc, lignosel\u00fclozun fiziksel bariyerini azaltmak i\u00e7in etkili bir y\u00f6ntem olarak kabul edilir ve basit haz\u0131rlama, ye\u015fil \u00e7evre koruma ve maliyet etkinli\u011fi avantajlar\u0131na sahiptir.
\nDES pH'a g\u00f6re \u00fc\u00e7 t\u00fcre ayr\u0131labilir: n\u00f6tr, asidik ve alkalin. Tan ve arkada\u015flar\u0131, n\u00f6tr, asidik ve alkali DES'in palmiye ya\u011f\u0131 bo\u015f meyve kabuklar\u0131ndan lignin \u00fczerindeki ekstraksiyon etkilerini kar\u015f\u0131la\u015ft\u0131r\u0131p analiz etmi\u015f ve asidik DES'in di\u011fer ikisinden daha g\u00fc\u00e7l\u00fc bir ekstraksiyon etkisine sahip oldu\u011funu bulmu\u015ftur. Asidik DES'te Tan ve arkada\u015flar\u0131, kolin klor\u00fcr laktik asit DES ile kar\u015f\u0131la\u015ft\u0131r\u0131ld\u0131\u011f\u0131nda, kolin klor\u00fcr laktik asit DES'ten ekstrakte edilen ligninin bir\u00e7ok \u03b2 - O-4 'ba\u011f\u0131 ve biyolojik olarak daha aktif b\u00f6lgeler i\u00e7erdi\u011fini bulmu\u015flard\u0131r. Bununla birlikte, kolin klor\u00fcr formik asit ligninin yap\u0131s\u0131 daha fazla zarar g\u00f6rm\u00fc\u015f ve daha fazla yo\u011funla\u015fma yap\u0131s\u0131 ortaya \u00e7\u0131km\u0131\u015ft\u0131r. Bu nedenle, kolin klor\u00fcr laktik asit DES'den ekstrakte edilen lignin daha ileri uygulamalar i\u00e7in daha uygundur. Bununla birlikte, \u015fu anda DES \u00e7\u00f6z\u00fcc\u00fclerinin bambu filizi kabu\u011fu hammaddelerinde lignin ekstraksiyonu i\u00e7in uygulanmas\u0131 konusunda \u00e7ok az ara\u015ft\u0131rma vard\u0131r. Sichuan Eyaleti, Zizhu'nun ekim alan\u0131n\u0131n 100000 hektara ula\u015ft\u0131\u011f\u0131 ve her y\u0131l b\u00fcy\u00fck miktarda bambu filizi kabu\u011fu at\u0131\u011f\u0131 \u00fcreten bol miktarda bambu kayna\u011f\u0131na sahiptir. Bu nedenle, bu \u00e7al\u0131\u015fmada, Neosinocalamus affinis bambu kabu\u011fu deneysel hammadde olarak kullan\u0131lm\u0131\u015f ve farkl\u0131 DES \u00e7\u00f6z\u00fcc\u00fc ko\u015fullar\u0131 (kolin klor\u00fcr ve laktik asit molar oran\u0131 s\u0131ras\u0131yla 1:3, 1:6, 1:9) ve s\u0131cakl\u0131k (90, 110, 130 \u2103) lignini \u00f6n i\u015fleme tabi tutmak i\u00e7in kullan\u0131lm\u0131\u015f ve daha sonra \u00f6\u011f\u00fct\u00fclm\u00fc\u015f lignin ve DES \u00e7\u00f6z\u00fcc\u00fcs\u00fc ile \u00f6n i\u015fleme tabi tutulmu\u015f lignin jel kromatografisi, k\u0131z\u0131l\u00f6tesi spektroskopisi, fosfor spektrumu, termogravimetri analizi ile kar\u015f\u0131la\u015ft\u0131r\u0131lm\u0131\u015f ve analiz edilmi\u015ftir, DES taraf\u0131ndan ekstrakte edilen ligninin yap\u0131s\u0131n\u0131 ve termal stabilitesini ara\u015ft\u0131rmak ve antioksidan aktivitenin g\u00fcc\u00fcn\u00fc daha fazla incelemek, b\u00f6ylece lignini ekstrakte etmek i\u00e7in uygun DES \u00e7\u00f6z\u00fcc\u00fc oran\u0131n\u0131 ve s\u0131cakl\u0131k ko\u015fullar\u0131n\u0131 bulmak, b\u00f6ylece bambu kabu\u011fu kaynaklar\u0131n\u0131n y\u00fcksek de\u011ferli kullan\u0131m\u0131 i\u00e7in yeni bir y\u00f6n sa\u011flamak.<\/p>\n

\"\"\"\"\"\"\"\"\"\"\"\"\"\"\"\"
\nBu \u00e7al\u0131\u015fmada CC-LA lignini ekstrakte etmek i\u00e7in d\u00fc\u015f\u00fck erime noktal\u0131 bir \u00e7\u00f6z\u00fcc\u00fc olarak kolin klor\u00fcr\/laktik asit kullan\u0131lm\u0131\u015ft\u0131r. Hafif ko\u015fullar alt\u0131nda: kolin klor\u00fcr\/laktik asit=1:6, s\u0131cakl\u0131k 110 \u2103, lignin verimi 62.32% idi ve bu di\u011fer d\u00fc\u015f\u00fck erime noktal\u0131 \u00e7\u00f6z\u00fcc\u00fclerden daha y\u00fcksekti. Bunun nedeni, kolin klor\u00fcr\/laktik asit DES \u00e7\u00f6zeltisinin Poaceae hammaddeleri i\u00e7in MWL (13.4%) veriminden \u00e7ok daha y\u00fcksek olan daha g\u00fc\u00e7l\u00fc bir ay\u0131rma kabiliyetine sahip olmas\u0131 ve bu ekstraksiyon y\u00f6nteminin bambu filiz kabuklar\u0131ndan lignin ekstraksiyonu i\u00e7in uygun oldu\u011funu g\u00f6stermesi olabilir. CC-LA ligninin molek\u00fcler a\u011f\u0131rl\u0131\u011f\u0131 nispeten d\u00fc\u015f\u00fckt\u00fcr, PDI<2 ve iyi bir homojenli\u011fe sahiptir, bu da lignin makromolek\u00fclleri \u00fczerindeki kimyasal ba\u011flar\u0131n d\u00fc\u015f\u00fck erime noktal\u0131 \u00e7\u00f6z\u00fcc\u00fclerle \u00f6n i\u015flemden sonra k\u0131r\u0131ld\u0131\u011f\u0131n\u0131 g\u00f6sterir. FI-TR ve 31P-NMR analizi ile CC-LA ligninin daha fazla polifenolik hidroksil grubu i\u00e7erdi\u011fi ve iyi termal stabiliteye sahip oldu\u011fu bulunmu\u015ftur. Ticari antioksidanlarla kar\u015f\u0131la\u015ft\u0131r\u0131ld\u0131\u011f\u0131nda, daha y\u00fcksek antioksidan aktiviteye sahiptir \u00e7\u00fcnk\u00fc ligninin antioksidan aktivitesi fenolik hidroksil gruplar\u0131n\u0131n i\u00e7eri\u011fi ile pozitif ili\u015fkilidir. Bu nedenle, CC-LA lignin g\u0131da, ila\u00e7 ve kozmetikte antioksidan olarak uygulanma potansiyeline sahiptir.<\/p>","protected":false},"excerpt":{"rendered":"

D\u00fc\u015f\u00fck erime noktal\u0131 \u00e7\u00f6z\u00fcc\u00fc \u00f6n i\u015fleminin bambu filizi kabu\u011fu lignininin yap\u0131s\u0131 ve fizikokimyasal \u00f6zellikleri \u00fczerindeki etkisi Lignin, fenilpropan yap\u0131sal birimlerinin oksidatif ba\u011flanmas\u0131yla olu\u015fan amorf do\u011fal bir polimerdir. Suda \u00e7\u00f6z\u00fcnmeyen diyet lifinin bile\u015fenlerinden biridir ve metoksi, fenolik hidroksil, alkol gibi aktif gruplar i\u00e7erir [...]<\/p>","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[20],"tags":[],"yoast_head":"\nThe effect of low melting point solvent pretreatment on the structure and physicochemical properties of bamboo shoot shell lignin - China Chemical Manufacturer<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/longchangextracts.com\/tr\/bamboo-shoot-shell-lignin\/\" \/>\n<meta property=\"og:locale\" content=\"tr_TR\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"The effect of low melting point solvent pretreatment on the structure and physicochemical properties of bamboo shoot shell lignin - China Chemical Manufacturer\" \/>\n<meta property=\"og:description\" content=\"The effect of low melting point solvent pretreatment on the structure and physicochemical properties of bamboo shoot shell lignin Lignin is an amorphous natural polymer formed by oxidative coupling of phenylpropane structural units. 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