{"id":7553,"date":"2024-08-06T20:29:54","date_gmt":"2024-08-06T20:29:54","guid":{"rendered":"https:\/\/longchangextracts.com\/?p=7553"},"modified":"2024-08-06T20:29:54","modified_gmt":"2024-08-06T20:29:54","slug":"bamboo-shoot-shell-lignin","status":"publish","type":"post","link":"https:\/\/longchangextracts.com\/hu\/bamboo-shoot-shell-lignin\/","title":{"rendered":"Az alacsony olvad\u00e1spont\u00fa old\u00f3szeres el\u0151kezel\u00e9s hat\u00e1sa a bambuszh\u00e9jh\u00e9j lignin szerkezet\u00e9re \u00e9s fizikai-k\u00e9miai tulajdons\u00e1gaira"},"content":{"rendered":"<p>Az alacsony olvad\u00e1spont\u00fa old\u00f3szeres el\u0151kezel\u00e9s hat\u00e1sa a bambuszh\u00e9jh\u00e9j lignin szerkezet\u00e9re \u00e9s fizikai-k\u00e9miai tulajdons\u00e1gaira<br \/>\nA lignin egy amorf term\u00e9szetes polimer, amely fenilprop\u00e1n szerkezeti egys\u00e9gek oxidat\u00edv \u00f6sszekapcsol\u00f3d\u00e1s\u00e1val j\u00f6n l\u00e9tre. A nem v\u00edzben old\u00f3d\u00f3 \u00e9lelmi rostok egyik \u00f6sszetev\u0151je, \u00e9s olyan akt\u00edv csoportokat tartalmaz, mint a metoxi, fenolos hidroxil, alkoholos hidroxil, karboxil stb. Magas biol\u00f3giai aktivit\u00e1ssal rendelkezik. Rodr \u00ed guez gut \u00e9 rrez \u00e9s t\u00e1rsai meg\u00e1llap\u00edtott\u00e1k, hogy a lignin er\u0151sebb adszorpci\u00f3s kapacit\u00e1ssal rendelkezik az epesavak sz\u00e1m\u00e1ra, mint a cellul\u00f3z \u00e9s a hemicellul\u00f3z; Gong \u00e9s t\u00e1rsai meg\u00e1llap\u00edtott\u00e1k, hogy a lignin az alfa-amil\u00e1z immobiliz\u00e1ci\u00f3s hordoz\u00f3jak\u00e9nt haszn\u00e1lhat\u00f3. A lignin er\u0151s biol\u00f3giai aktivit\u00e1ssal is rendelkezik, mint p\u00e9ld\u00e1ul antioxid\u00e1ns, antibakteri\u00e1lis, UV-ellen\u00e1ll\u00f3, f\u00e9nyv\u00e9d\u0151 \u00e9s b\u0151r\u00e1pol\u00f3, valamint a b\u0151rr\u00e1k g\u00e1tl\u00e1sa. J\u00f3 biokompatibilit\u00e1ssal rendelkezik, \u00e9s potenci\u00e1lisan alkalmazhat\u00f3 az \u00e9lelmiszer- \u00e9s kozmetikai iparban.<br \/>\nEddig egy sor k\u00e9miai, mechanikai \u00e9s biol\u00f3giai el\u0151kezel\u00e9si technik\u00e1t alkalmaztak a lignin kinyer\u00e9s\u00e9re, bele\u00e9rtve a g\u0151zrobban\u00e1st, a szerves old\u00f3szeres el\u0151kezel\u00e9st \u00e9s a m\u00e9ly eutektikus old\u00f3szeres (DES) el\u0151kezel\u00e9si m\u00f3dszereket. A lignin lev\u00e1laszt\u00e1s\u00e1ra szolg\u00e1l\u00f3 k\u00e9miai m\u00f3dszerek azonban er\u0151s savakat vagy b\u00e1zisokat, valamint magas h\u0151m\u00e9rs\u00e9kletet \u00e9s nyom\u00e1st ig\u00e9nyelnek, amelyek k\u00f6rnyezetszennyez\u00e9st okozhatnak. A biol\u00f3giai m\u00f3dszereket gyakran korl\u00e1tozza a h\u0151m\u00e9rs\u00e9klet \u00e9s a biol\u00f3giai aktivit\u00e1s bizonytalans\u00e1ga. A DES, m\u00e1s n\u00e9ven alacsony olvad\u00e1s\u00fa old\u00f3szerek vagy ionos folyad\u00e9kok, hidrog\u00e9nk\u00f6t\u00e9s-donorokb\u00f3l \u00e9s -akceptorokb\u00f3l \u00e1ll\u00f3 alacsony olvad\u00e1s\u00fa kever\u00e9k. Ma \u00e9s munkat\u00e1rsai kutat\u00e1sai kimutatt\u00e1k, hogy a DES old\u00f3szerek nemcsak a lignint oldj\u00e1k hat\u00e9konyan, hanem a cellul\u00f3zt is alig oldj\u00e1k. Fizikai \u00e9s k\u00e9miai tulajdons\u00e1gai miatt a DES old\u00f3szer olvad\u00e1spontja alacsonyabb, mint b\u00e1rmelyik komponens\u00e9, \u00e9s szobah\u0151m\u00e9rs\u00e9kleten foly\u00e9kony eutektikus rendszer. A DES old\u00f3szert hat\u00e9kony m\u00f3dszernek tekintik a lignocellul\u00f3z fizikai g\u00e1tj\u00e1nak cs\u00f6kkent\u00e9s\u00e9re, \u00e9s el\u0151nye az egyszer\u0171 el\u0151\u00e1ll\u00edt\u00e1s, a z\u00f6ld k\u00f6rnyezetv\u00e9delem \u00e9s a k\u00f6lts\u00e9ghat\u00e9konys\u00e1g.<br \/>\nA DES pH alapj\u00e1n h\u00e1rom t\u00edpusba sorolhat\u00f3: semleges, savas \u00e9s l\u00fagos. Tan \u00e9s munkat\u00e1rsai \u00f6sszehasonl\u00edtott\u00e1k \u00e9s elemezt\u00e9k a semleges, savas \u00e9s l\u00fagos DES extrakci\u00f3s hat\u00e1s\u00e1t az olajp\u00e1lma \u00fcres gy\u00fcm\u00f6lcsh\u00e9j\u00e1b\u00f3l sz\u00e1rmaz\u00f3 ligninre, \u00e9s meg\u00e1llap\u00edtott\u00e1k, hogy a savas DES er\u0151sebb extrakci\u00f3s hat\u00e1ssal rendelkezik, mint a m\u00e1sik kett\u0151. A savas DES eset\u00e9ben Tan \u00e9s munkat\u00e1rsai meg\u00e1llap\u00edtott\u00e1k, hogy a kolinklorid-tejsavas DES-sel \u00f6sszehasonl\u00edtva a kolinklorid-tejsavas DES-b\u0151l kivont lignin sok \u03b2-O-4 'k\u00f6t\u00e9st \u00e9s t\u00f6bb biol\u00f3giailag akt\u00edv helyet tartalmaz. A kolinklorid hangyasavas lignin szerkezete azonban jobban k\u00e1rosodott, ami t\u00f6bb kondenz\u00e1ci\u00f3s strukt\u00far\u00e1t eredm\u00e9nyez. Ez\u00e9rt a kolinklorid-tejsavas DES-b\u0151l kivont lignin alkalmasabb a tov\u00e1bbi alkalmaz\u00e1sra. Jelenleg azonban kev\u00e9s kutat\u00e1s foglalkozik a DES old\u00f3szerek alkalmaz\u00e1s\u00e1val a bambuszhajt\u00e1sh\u00e9j nyersanyag\u00e1ban a lignin kivon\u00e1s\u00e1ra. Szecsu\u00e1n tartom\u00e1ny b\u0151s\u00e9ges bambuszk\u00e9szletekkel rendelkezik, amelyek k\u00f6z\u00fcl a Zizhu term\u0151ter\u00fclete el\u00e9rte a 100000 hekt\u00e1rt, ami \u00e9vente hatalmas mennyis\u00e9g\u0171 bambuszh\u00e9j-hullad\u00e9kot termel. Ez\u00e9rt ebben a tanulm\u00e1nyban a Neosinocalamus affinis bambuszh\u00e9j\u00e1t haszn\u00e1lt\u00e1k k\u00eds\u00e9rleti nyersanyagk\u00e9nt, \u00e9s a DES old\u00f3szer k\u00fcl\u00f6nb\u00f6z\u0151 k\u00f6r\u00fclm\u00e9nyeit (a kolin-klorid \u00e9s a tejsav m\u00f3lar\u00e1nya 1:3, 1:6, 1:9) \u00e9s a h\u0151m\u00e9rs\u00e9klet (90, 110, 130 \u2103) a lignin el\u0151kezel\u00e9s\u00e9hez, majd az \u0151r\u00f6lt lignint \u00e9s a DES old\u00f3szerrel el\u0151kezelt lignint \u00f6sszehasonl\u00edtottuk \u00e9s g\u00e9lkromatogr\u00e1fi\u00e1val, infrav\u00f6r\u00f6s spektroszk\u00f3pi\u00e1val, foszforspektrummal, termogravimetri\u00e1s elemz\u00e9ssel elemezt\u00fck, a DES \u00e1ltal extrah\u00e1lt lignin szerkezet\u00e9nek \u00e9s termikus stabilit\u00e1s\u00e1nak felt\u00e1r\u00e1sa, valamint az antioxid\u00e1ns aktivit\u00e1s er\u0151ss\u00e9g\u00e9nek tov\u00e1bbi tanulm\u00e1nyoz\u00e1sa, a DES old\u00f3szer megfelel\u0151 ar\u00e1ny\u00e1nak \u00e9s a lignin extrah\u00e1l\u00e1s\u00e1nak h\u0151m\u00e9rs\u00e9kleti felt\u00e9teleinek megtal\u00e1l\u00e1sa \u00e9rdek\u00e9ben, hogy \u00faj ir\u00e1nyt adjon a bambuszh\u00e9j-forr\u00e1sok nagy \u00e9rt\u00e9k\u0171 hasznos\u00edt\u00e1s\u00e1nak.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-7554\" src=\"https:\/\/longchangextracts.com\/wp-content\/uploads\/2024\/08\/1-314.png\" alt=\"\" width=\"340\" height=\"320\" \/><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-7555\" src=\"https:\/\/longchangextracts.com\/wp-content\/uploads\/2024\/08\/2-266.png\" alt=\"\" width=\"350\" height=\"218\" \/><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-7556\" src=\"https:\/\/longchangextracts.com\/wp-content\/uploads\/2024\/08\/3-251.png\" alt=\"\" width=\"344\" height=\"241\" \/><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-7557\" src=\"https:\/\/longchangextracts.com\/wp-content\/uploads\/2024\/08\/4-231.png\" alt=\"\" width=\"338\" height=\"365\" \/><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-7558\" src=\"https:\/\/longchangextracts.com\/wp-content\/uploads\/2024\/08\/5-207.png\" alt=\"\" width=\"666\" height=\"295\" \/><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-7559\" src=\"https:\/\/longchangextracts.com\/wp-content\/uploads\/2024\/08\/6-190.png\" alt=\"\" width=\"708\" height=\"260\" \/><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-7560\" src=\"https:\/\/longchangextracts.com\/wp-content\/uploads\/2024\/08\/7-174.png\" alt=\"\" width=\"351\" height=\"252\" \/><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-7561\" src=\"https:\/\/longchangextracts.com\/wp-content\/uploads\/2024\/08\/8-155.png\" alt=\"\" width=\"353\" height=\"213\" \/><br \/>\nEbben a tanulm\u00e1nyban a CC-LA lignin kivon\u00e1s\u00e1hoz alacsony olvad\u00e1spont\u00fa old\u00f3szerk\u00e9nt kolinkloridot\/tejsavat haszn\u00e1ltak. Enyhe k\u00f6r\u00fclm\u00e9nyek k\u00f6z\u00f6tt: kolinklorid\/tejsav=1:6, h\u0151m\u00e9rs\u00e9klet 110 \u2103, a ligninhozam 62,32% volt, ami magasabb volt, mint m\u00e1s alacsony olvad\u00e1spont\u00fa old\u00f3szerek\u00e9. Ennek oka az lehet, hogy a kolinklorid\/tejsav DES oldat er\u0151sebb elv\u00e1laszt\u00f3 k\u00e9pess\u00e9ggel rendelkezik a Poaceae nyersanyagok eset\u00e9ben, j\u00f3val nagyobb, mint az MWL hozama (13,4%), ami azt jelzi, hogy ez az extrakci\u00f3s m\u00f3dszer alkalmas a lignin bambuszhajt\u00e1s h\u00e9j\u00e1b\u00f3l t\u00f6rt\u00e9n\u0151 kivon\u00e1s\u00e1ra. A CC-LA lignin molekulat\u00f6mege viszonylag alacsony, PDI&lt;2 \u00e9s j\u00f3 egyenletess\u00e9g\u0171, ami azt jelzi, hogy a lignin makromolekul\u00e1in l\u00e9v\u0151 k\u00e9miai k\u00f6t\u00e9sek az alacsony olvad\u00e1spont\u00fa old\u00f3szerekkel t\u00f6rt\u00e9n\u0151 el\u0151kezel\u00e9s ut\u00e1n felbomlanak. FI-TR \u00e9s 31P-NMR elemz\u00e9ssel meg\u00e1llap\u00edtott\u00e1k, hogy a CC-LA lignin t\u00f6bb polifenolos hidroxilcsoportot tartalmaz \u00e9s j\u00f3 h\u0151stabilit\u00e1ssal rendelkezik. A kereskedelmi antioxid\u00e1nsokkal \u00f6sszehasonl\u00edtva magasabb antioxid\u00e1ns aktivit\u00e1ssal rendelkezik, mivel a lignin antioxid\u00e1ns aktivit\u00e1sa pozit\u00edvan korrel\u00e1l a fenolos hidroxilcsoportok tartalm\u00e1val. Ez\u00e9rt a CC-LA lignin antioxid\u00e1nsk\u00e9nt alkalmazhat\u00f3 \u00e9lelmiszerekben, gy\u00f3gyszerekben \u00e9s kozmetikumokban.<\/p>","protected":false},"excerpt":{"rendered":"<p>The effect of low melting point solvent pretreatment on the structure and physicochemical properties of bamboo shoot shell lignin Lignin is an amorphous natural polymer formed by oxidative coupling of phenylpropane structural units. It is one of the components of non water soluble dietary fiber and contains active groups such as methoxy, phenolic hydroxyl, alcohol [&hellip;]<\/p>","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[20],"tags":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v23.0 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>The effect of low melting point solvent pretreatment on the structure and physicochemical properties of bamboo shoot shell lignin - China Chemical Manufacturer<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/longchangextracts.com\/hu\/bamboo-shoot-shell-lignin\/\" \/>\n<meta property=\"og:locale\" content=\"hu_HU\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"The effect of low melting point solvent pretreatment on the structure and physicochemical properties of bamboo shoot shell lignin - China Chemical Manufacturer\" \/>\n<meta property=\"og:description\" content=\"The effect of low melting point solvent pretreatment on the structure and physicochemical properties of bamboo shoot shell lignin Lignin is an amorphous natural polymer formed by oxidative coupling of phenylpropane structural units. 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